High-valent iron porphyrins
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Avram Gold; Raymond Weiss
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Article
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2000
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John Wiley and Sons
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English
⚖ 101 KB
The term ‘high-valent’ refers to iron complexes of porphyrins and related macrocycles in which the oxidation state of the iron center exceeds III. High-valent iron porphyrins and chlorins are important biological transients whose intermediacy has been demonstrated in numerous peroxidase and catalase