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Valence-tautomerism in high-valent iron and manganese porphyrins

✍ Scribed by Raymond Weiss; Véronique Bulach; Avram Gold; James Terner; Alfred X. Trautwein


Book ID
106233073
Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
174 KB
Volume
6
Category
Article
ISSN
1432-1327

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High-valent iron porphyrins
✍ Avram Gold; Raymond Weiss 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 101 KB

The term ‘high-valent’ refers to iron complexes of porphyrins and related macrocycles in which the oxidation state of the iron center exceeds III. High-valent iron porphyrins and chlorins are important biological transients whose intermediacy has been demonstrated in numerous peroxidase and catalase