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Vacuum ultraviolet spectrum of carbonyl selenide, OCSe

✍ Scribed by Stephen Cradock; Robert J. Donovan; William Duncan; Harold M. Gillespie

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 349 KB
Volume: 31
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)85036-6

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✦ Synopsis

The h~ain features in the electronic spectrum of OCSe in the vaauum ultraviolet region (A = 200-118 nm) are reported and assigned. Bands of overlapping Rydberg series etiibit extiemely complex structure involving spin-orbit coupling (ca. 1800 cm-'), weak excitation of the high frequency stretchi@ vibr:;tion (ca 2100 cm-') and progressions and sequences in the low frequency stretch (ca. 500 cni-*). Wit\ the help of the He 1 photoelectron spectrum Rydberg series, which corre- spend to Rydberg levels closely similar to those of 'AC SC atom and of CSe2, are assigned. Suggested assignments of the remaining stroni features to intra-valence transitions aro.made.

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