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Vacuum ultraviolet photolysis of methane. Reaction of methylene

✍ Scribed by R.E. Rebbert; S.G. Lias; P. Ausloos

Publisher: Elsevier Science
Year: 1971
Tongue: English
Weight: 367 KB
Volume: 12
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(71)85076-5

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✦ Synopsis

Methylene zadicak formed in the pho!olysis of methane (123.6 and 104.8-106.7 nm) intnscrt into the C-H bond of methane to produce ethane molecules whose lifetime is independent of the energy of the photon. DeactiMtion of ethane by collision with methane is stepwise. and the lifetime of the insertion product is shorter than reported in previous CH2CO photolysis studies.

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