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Vacuum ultraviolet photolysis of CClF2CH2Cl

✍ Scribed by Tadahiro Minamikawa; Seido Ogura; Tetsuo Sakka; Yukio Ogata; Matae Iwasaki

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
540 KB
Volume
26
Category
Article
ISSN
0538-8066

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✦ Synopsis

Photolysis of CClFzCHzCl was studied by 147 nm vacuum ultraviolet irradiation. In the presence of NO; CFzCHz, CFZCHC1, and CClFzCN were produced. These products represent three different reaction paths; the molecular dechlorination, molecular dehydrochlorination, and chlorine radical elimination reactions. The reactant pressure and the addition gas (He or NO) pressure effects upon the product yield were studied.

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