✦ LIBER ✦

Vacuum Dynamic Gas-Phase/Solid-Phase Reactions: N-Chlorination of Primary Amines and the α-Elimination of the Resulting Chloramines: Access to Reactive (E)- and (Z)-Aldimines

✍ Scribed by Jean-Claude Guillemin; Dr. Jean-Marc Denis

Publisher: John Wiley and Sons
Year: 1982
Tongue: English
Weight: 250 KB
Volume: 21
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198215150

No coin nor oath required. For personal study only.

✦ Synopsis

Vacuum dynamic gaslsolid phase reactions have been recently used to synthesize reactives molecules I l l . We report here the direct synthesis of reactive Kunsubstituted (E)-and (2)aldimines 3 and 4 by a multistep sequence carried out i n a single vacuum line :

Kchlorination of Primary amines 1 on solid kchlorosuccinimide (NCS) and the following =-elimination of the resulting Kchloramines 2 over the solid potassiumi-butoxide (KGt-Bu) (scheme 1 ) .

📜 SIMILAR VOLUMES

Vacuum Dynamic Gas Phase/Solid-Phase Rea

Vacuum Dynamic Gas Phase/Solid-Phase Reactions: N-Chlorination of Primary Amines and α-Elimination of the Resulting Chloramines; Synthesis of Reactive (E)- and (Z)-Aldimines

✍ Jean-Claude Guillemin; Dr. Jean-Marc Denis 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 128 KB 👁 2 views

## Abstract The complete manuscript of this communication appears in: __Angew. Chem. Suppl. 1982__, 1515. DOI:10.1002/anie.198215150