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Vacuum Dynamic Gas Phase/Solid-Phase Reactions: N-Chlorination of Primary Amines and α-Elimination of the Resulting Chloramines; Synthesis of Reactive (E)- and (Z)-Aldimines

✍ Scribed by Jean-Claude Guillemin; Dr. Jean-Marc Denis

Publisher: John Wiley and Sons
Year: 1982
Tongue: English
Weight: 128 KB
Volume: 21
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198206901

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✦ Synopsis

Abstract

The complete manuscript of this communication appears in: Angew. Chem. Suppl. 1982, 1515. DOI:10.1002/anie.198215150

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Vacuum Dynamic Gas-Phase/Solid-Phase Rea

Vacuum Dynamic Gas-Phase/Solid-Phase Reactions: N-Chlorination of Primary Amines and the α-Elimination of the Resulting Chloramines: Access to Reactive (E)- and (Z)-Aldimines

✍ Jean-Claude Guillemin; Dr. Jean-Marc Denis 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 250 KB 👁 1 views

Vacuum dynamic gaslsolid phase reactions have been recently used to synthesize reactives molecules I l l . We report here the direct synthesis of reactive Kunsubstituted (E)-and (2)aldimines 3 and 4 by a multistep sequence carried out i n a single vacuum line : Kchlorination of Primary amines 1 on