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UV photoelectron spectroscopy of matrix-isolated and condensed CO and N2

✍ Scribed by D. Schmeisser; K. Jacobi

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
546 KB
Volume
62
Category
Article
ISSN
0009-2614

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✦ Synopsis

UV photoelectron spectra of matrix-isolated and condensed CO and Nz bake been measured. The emission from the 40, 1~ and So orbit& show similar relauxtron shifts of about 1 eV This shift is 0.3 eV larger for the species isolated in xenon matrices. The width of the pe&s is sm&er by 0.3 eV in the Se matrix in comparison with the pure solids but remains larger than those measured for the gx phase.

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High resolution photoelectron spectra have been recorded from N2 and CO with a fuliy caiibrated energy anafyzer at both the 736 and 744 A Nel lines. Observation of electrons from transitions to the u = 11 level of the CO+ X\*C+ ground state is reported for the fast time. Relative intensities of all