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Photoelectron spectroscopy of N2 and CO with dispersed Nel radiation

✍ Scribed by J.L. Gardner; James A.R. Samson


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
245 KB
Volume
26
Category
Article
ISSN
0009-2614

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✦ Synopsis


High resolution photoelectron spectra have been recorded from N2 and CO with a fuliy caiibrated energy anafyzer at both the 736 and 744 A Nel lines. Observation of electrons from transitions to the u = 11 level of the CO+ X*C+ ground state is reported for the fast time. Relative intensities of all vibrational peaks appearing in each spectrum are given.


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UV photoelectron spectra of matrix-isolated and condensed CO and Nz bake been measured. The emission from the 40, 1~ and So orbit& show similar relauxtron shifts of about 1 eV This shift is 0.3 eV larger for the species isolated in xenon matrices. The width of the pe&s is sm&er by 0.3 eV in the Se m