## Abstract Expansion of TATB is studied on a molecular level by means of xβray crystallography. Continuous monitoring of the cell constants of TATB between 214 K and 377 K allows calculation of a volume change of +5.1% for this molecular system. Expansion of the pure material is almost exclusively
UV-Induced Degradation Rates of 1,3,5-Triamino-2,4,6-Trinitrobenzene (TATB)
β Scribed by Williams, Darren L.; Timmons, James C.; Woodyard, James D.; Rainwater, Ken A.; Lightfoot, James M.; Richardson, Ben R.; Burgess, Caroline E.; Heh, John L.
- Book ID
- 111982143
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 54 KB
- Volume
- 107
- Category
- Article
- ISSN
- 1089-5639
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A new, three-stage synthesis of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) has been developed which avoids the use of halogenated precursors or reagents. The starting material, 1,3,5trihydroxy-benzene, is converted via the sequence nitrationalkylation-amination to TATB in an overall yield of 87%. T
The products of sublimation and thermal decomposition of 1,3,5-triamino-2,4,6-trinitmbenzene have been determined mass spectrometrically in the temperature range 200-300Β°C employing both the effusion and Langmuir evaporation methods. Electron impact ionization energies 1-2 eV above appearance potent
The mid-infrared (4-00 cm-I) spectra in KBr matrix of the title compound (TATB) and four of its isotopic derivatives have been analysed for the purpose of vibrational assignments. The relative simplicity of the spectra, in conjunction with the various isotopic shifts, indicates that thirteen of the