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UV-Induced Degradation Rates of 1,3,5-Triamino-2,4,6-Trinitrobenzene (TATB)

✍ Scribed by Williams, Darren L.; Timmons, James C.; Woodyard, James D.; Rainwater, Ken A.; Lightfoot, James M.; Richardson, Ben R.; Burgess, Caroline E.; Heh, John L.


Book ID
111982143
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
54 KB
Volume
107
Category
Article
ISSN
1089-5639

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## Abstract Expansion of TATB is studied on a molecular level by means of x‐ray crystallography. Continuous monitoring of the cell constants of TATB between 214 K and 377 K allows calculation of a volume change of +5.1% for this molecular system. Expansion of the pure material is almost exclusively

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A new, three-stage synthesis of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) has been developed which avoids the use of halogenated precursors or reagents. The starting material, 1,3,5trihydroxy-benzene, is converted via the sequence nitrationalkylation-amination to TATB in an overall yield of 87%. T

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The mid-infrared (4-00 cm-I) spectra in KBr matrix of the title compound (TATB) and four of its isotopic derivatives have been analysed for the purpose of vibrational assignments. The relative simplicity of the spectra, in conjunction with the various isotopic shifts, indicates that thirteen of the