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Crystal State of 1,3,5-Triamino-2,4,6-Trinitrobenzene (TATB) Undergoing Thermal Cycling Process

✍ Scribed by Sun, Jie; Kang, Bin; Xue, Chao; Liu, Yu; Xia, Yunxia; Liu, Xiaofeng; Zhang, Wei


Book ID
120992713
Publisher
Taylor and Francis Group
Year
2010
Tongue
English
Weight
396 KB
Volume
28
Category
Article
ISSN
0737-0652

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## Abstract Expansion of TATB is studied on a molecular level by means of x‐ray crystallography. Continuous monitoring of the cell constants of TATB between 214 K and 377 K allows calculation of a volume change of +5.1% for this molecular system. Expansion of the pure material is almost exclusively

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A new, three-stage synthesis of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) has been developed which avoids the use of halogenated precursors or reagents. The starting material, 1,3,5trihydroxy-benzene, is converted via the sequence nitrationalkylation-amination to TATB in an overall yield of 87%. T

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