## Abstract The UV./VIS. absorption spectrum of [18]annulene has been remeasured in 3‐rnethylpentane at room and at liquid nitrogen (glass) temperature and interpreted by the CNDO/S‐CI‐method. The confrontation of the experimental electronic transitions with the CNDO/S‐CI‐calculated ones favors a s
✦ LIBER ✦
UV absorption spectrum of low-temperature matrix-isolated NFCl radicals
✍ Scribed by Julanna V. Gilbert; Ann M. Zarubaiko; Stephen Lantz
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 222 KB
- Volume
- 220
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The ultraviolet absorption spectrum of NFCI radicals isolated in a low-temperature argon matrix was obtained. The absorption spectrum extends from 300 to 400 nm with a maximum at 360 nm. It consists of several partially resolved bands with an average band separation of 340 + 20 cm-t and is assigned to a transition from the ground state to the first excited electronic state involving a progression in v2, the bending mode.
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