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Uses of SiN bonds in synthesis: Easy routes to functional protected primary amines from propargylic silylamines

✍ Scribed by Robert J.P. Corriu; Vilam Huynh; Javed Iqbal; Joël J.E. Moreau

Book ID: 103223962
Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 254 KB
Volume: 276
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(84)80666-x

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Uses of SiN bonds in organic synthesis.

Uses of SiN bonds in organic synthesis. A direct synthesis of functional protected propargylic primary amines.

✍ Robert J.P. Corriu; Vilam Huynh; Joël J.E. Moreau 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 214 KB

An easy route to lithium N,N-bis(trimethylsilyl)aminomethylacetylide 2. is described. Reactions of k with electrophiles give rise to various protected primary amines.