Uses of SiN bonds in organic synthesis. A direct synthesis of functional protected propargylic primary amines.

✍ Scribed by Robert J.P. Corriu; Vilam Huynh; Joël J.E. Moreau

• Book ID: 104241319
• Publisher: Elsevier Science
• Year: 1984
• Tongue: French
• Weight: 214 KB
• Volume: 25
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)90067-x

✦ Synopsis

An easy route to lithium N,N-bis(trimethylsilyl)aminomethylacetylide 2. is described.

Reactions of k with electrophiles give rise to various protected primary amines.