Use of transient and steady- state measurements of the unidirectional flux ratio for the determination of the free energy change of chemical reactions and active transport systems

Determination of the activation barrier

Determination of the activation barrier to energy transfer from 3ππ* to charge transfer levels via steady-state and transient luminescence measurements on bis(4-chlorothiophenol)(1,10-phenanthroline)zinc(II)

✍ R.G. Highland; G.A. Crosby 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 324 KB

The effect of rcmpcr~mre on the lummescence m~cns~~ and excrrcd stale lircllmrs of rhc r~dc compound is inwrpreled in terms or a barrier LO the IKUISTIX or energy rrom the IOUT\_Q %e lerel IO loner-lying charge-transfer Icvcl~ FIIS or an Arrhenius expression LO borh Ilrclimes and relawe tnrenslttcs