✦ LIBER ✦
Determination of the activation barrier to energy transfer from 3ππ* to charge transfer levels via steady-state and transient luminescence measurements on bis(4-chlorothiophenol)(1,10-phenanthroline)zinc(II)
✍ Scribed by R.G. Highland; G.A. Crosby
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 324 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The effect of rcmpcr~mre on the lummescence m~cns~~ and excrrcd stale lircllmrs of rhc r~dc compound is inwrpreled in terms or a barrier LO the IKUISTIX or energy rrom the IOUT_Q %e lerel IO loner-lying charge-transfer Icvcl~ FIIS or an Arrhenius expression LO borh Ilrclimes and relawe tnrenslttcs gleld an ncGvJGon energy and pre-exponential factor of = 140 cm-' and = 1 X 10' 3-l. respecuvely.