✦ LIBER ✦

Use of the Mössbauer isomer shift and the X-ray emission Kα shift to estimate the effective electronic population of iron in complexes

✍ Scribed by J. Blomquist; B. Roos; M. Sundbom

Publisher: Elsevier Science
Year: 1971
Tongue: English
Weight: 272 KB
Volume: 9
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(71)80213-0

No coin nor oath required. For personal study only.

✦ Synopsis

The Hartree-Fock method is used to calculate the KG trawition energy for a number of configurations of different Fe ions. Experimental X-ray emission G shifts are combined with Massbauer isomer shifts to estimate the effective mtiguratioae of the iron ion.

📜 SIMILAR VOLUMES

Mössbauer effect and magnetism down to 1

Mössbauer effect and magnetism down to 1.2°K in the triplet ground state of an iron(II)—phenanthroline complex

✍ E. König; B. Kanellakopulos 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 312 KB

Magnetic suswptibilities down to 1.2"K and 57Fe Miissbauer spectra at 42°K are reported on [Fe(pten)2 OR] \* 5H20. The results are consistent with a 3Az(~z~2~~)ground state characterized by a zero-field splitting of D = 4.150 cm-' into an upper !&Ys= +l) and a lower 10) level andg = 2.80. In reasona