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Use of the Lambert — Beer law in determining the NO2concentration in the system N2O4⇌ 2NO2⇌ 2NO + O2at high temperatures and pressures

✍ Scribed by M. Kh. Grishchuk

Publisher
Springer US
Year
1971
Tongue
English
Weight
341 KB
Volume
15
Category
Article
ISSN
0021-9037

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A spectroscopic study of the equilibrium
A spectroscopic study of the equilibrium NO2 + NO3 + M 2 N2O5 + M and the kinetics of the O3/N2O5/NO3/NO2/ air system
✍ J. Hjorth; J. Notholt; G. Restelli 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 865 KB

The equilibrium constant, K,, of the reaction NO2 + NO3 + M N z O ~ + M has been determined for a small range of temperatures around room temperature in air at 740 torr by direct spectroscopical measurements of NOz, NOS, and NzOs. At 298 K, K, was determined as (3.73 2 0.61) x lo-'' cm3 molecule-'.