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Use of the kinetic isotope effect as a test for homogeneous unimolecular gas phase reactions in thermolytic processes

✍ Scribed by Chickos, James S.


Book ID
127315520
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
579 KB
Volume
41
Category
Article
ISSN
0022-3263

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## Abstract Using H‐atoms produced in the radiolysis of water vapour, we determined the kinetic isotope effect for the reaction where RH and Rβ€²D are methylcyclohexane and perdeuterated methylcyclohexane, respectively. The result obtained from the isotope competitive method can be expressed with th