𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Use of (S)-(+)-1-aminoindan, (S)-(+)-1-indanol and (1R, 2S)-(+)-cis-1-amino-2-indanol as chiral modifiers in the enantioselective hydrogenation of ethyl pyruvate with Pt/SiO2 catalysts

✍ Scribed by Andrea B. Merlo; José F. Ruggera; Gerardo F. Santori; Albertina Moglioni; Graciela Y. Moltrasio Iglesias; Mónica L. Casella; Osmar A. Ferretti


Book ID
118427449
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
392 KB
Volume
133-135
Category
Article
ISSN
0920-5861

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The dependency of the enantioselectivity on the solvent and hydride source for the asymmetric reduction of acetophenone catalysed by the oxazaborolidine derived from cis-(1R,2S)-1-amino-indan-2-ol have been investigated. 11 B NMR studies have implied that monomer/dimer ratios are important for achie