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Use of reductive properties of iodotrichlorosilane II: Chemoselective reduction of α,β-unsaturated ketones and nitriles

✍ Scribed by Saad S. Elmorsy; Abdel-Aziz S. El-Ahl; Hanan Soliman; Fathy A. Amer

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
126 KB
Volume
37
Category
Article
ISSN
0040-4039

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The Clemmensen Reduction of α, β-Unsatur
The Clemmensen Reduction of α, β-Unsaturated Ketones
✍ Charles W. Jefford; André F. Boschung 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 German ⚖ 525 KB

## Abstract Eleven structurally different α, β‐unsaturated ketones were subjected to the __Clemmensen__ reduction under anhydrous conditions using amalgamated zinc, hydrogen chloride in a solution of ethyl ether, and acetic anhydride. In all cases but one the formation of cyclopropyl acetates was o