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Use of isotopes for studying reaction mechanisms

✍ Scribed by Uday Maitra; J. Chandrasekhar

Book ID
107590053
Publisher
Indian Academy of Sciences
Year
2011
Tongue
English
Weight
201 KB
Volume
16
Category
Article
ISSN
0971-8044

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## Abstract The use of kinetic isotope effects (KIEs) for the short‐lived radionuclides ^11^C and ^18^F in the study of reaction mechanisms is described using some examples. Leaving group fluorine KIEs (__k__^18^/__k__^19^) have been utilized to determine the rate‐limiting step for nucleophilic aro