Use of infrared spectroscopy to measure the rate of the isotopic exchange of hydrogen between molecules of alcohol and thiol
β Scribed by G. S. Denisov; E. M. Kazakova; E. V. Ryl'tsev
- Book ID
- 104832252
- Publisher
- Springer US
- Year
- 1968
- Tongue
- English
- Weight
- 164 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0021-9037
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## Abstract Multistep hydrogen isotope exchange reactions, such as the Γonization of a carbon acid via a carbanion intermediate in a protic solvent, when conducted using an isotopic tracer to monitor the exchange, have the unusual feature that their rateβdetermining steps always refer to the transf
The temperature dependence of the rate constant for the exchange reaction between oxygen atoms and dioxygen molecules has been studied using the oxygen isotopes and . The reaction was studied by VIS-photolysis of ozone in the presence of isotopic 16 18 O O dioxygen and with nitrogen as a bath gas a