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Use of colloidal ruthenium particles in the electrochemical reduction of benzene by solvated electrons

✍ Scribed by J. Foise; R. Kershaw; K. Dwight; A. Wold


Book ID
113186943
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
268 KB
Volume
20
Category
Article
ISSN
0025-5408

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Photoinduced interfacial electron transfer from the conduction band of colloidal TiOl semiconductor particles to the cofacial dimeric viologen DV"+, an electron acceptor, occurs in the picosecond time domain. The interfacial electron-transfer rate constant is about 2x 10" SK' at pH 7.8. The reaction