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Use of carbonylditriazole in peptide synthesis

✍ Scribed by H. C. Beyerman; W. Maassen van Den Brink

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
201 KB
Volume
80
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

N,N′‐Carbonyldi‐s‐triazole is shown to be a useful peptide‐forming reagent. Advantages over other reagents are: (1) low degree of racemization, (2) applicability in dimethylformamide, a solvent for both small and large peptides.

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Practical procedures have been developed for synthesis of peptides using lipases and esterases as catalysts. We describe here a new strategy for enzymatic peptide synthesis using an esterase without amidase activity as a catalyst and N-acyl amino acid esters and amino acid esters as substrates in e