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Use of Alkene Chloronium Intermediates in Organic Synthesis. Two New Reactions of Alkene Chloronium Ions

โœ Scribed by Sumrell, Gene; Howell, Ronald G.; Wyman, Bert M.; Harvey, Mack C.


Book ID
127039581
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
760 KB
Volume
30
Category
Article
ISSN
0022-3263

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In the presence of HX, carbanions MeseBCHLiRl react with afiphatic aldehydes to give alkenes. The stereochemistry of the product alkene depends upon the nature of HX. In our previous paper1 we showed that in the presence of TFAA or NCS, anions (1) (W&H) yield ketones rather than alkenes when react