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Use of a Polyhedral Oligomeric Silsesquioxane (POSS)-Imidazolium Cation as an Organic Modifier for Montmorillonite

✍ Scribed by Fox, Douglas M.; Maupin, Paul H.; Harris,, Richard H.; Gilman, Jeffrey W.; Eldred, Donald V.; Katsoulis, Dimi; Trulove, Paul C.; De Long, Hugh C.

Book ID: 120837409
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 253 KB
Volume: 23
Category: Article
ISSN: 0743-7463
DOI: 10.1021/la0636863

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The use of polyhedral oligomeric silsesquioxane (POSS) as a soluble support for use in organic synthesis is reported. A POSS-bound isocyanate was readily synthesised in one step from commercially available starting materials and isolated in high yield and purity by simple filtration. It was found to

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