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Use of a free-expansion jet in ultra-high-resolution inverse raman spectroscopy

✍ Scribed by James J. Valentini; Peter Esherick; Adelbert Owyoung

Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 247 KB
Volume: 75
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(80)80586-0

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✦ Synopsis

RotatIonally resolved, ultra-tigh-resolution mverse Raman spectra of CH4 have been obtamed m a free-expansion Jet. Usmg relatively mdd expansion conditions a pure methane Jet has been cooled to a rotational temperature of 13 K The hmltmg rotatlonal state populations observed, however, are not Boltzmann because of nuclear spm effects

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