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Up-conversion Luminescence in Dye-Doped Crystals of Potassium Hydrogen Phthalate

✍ Scribed by J.B. Benedict; P.M. Wallace; P.J. Reid; S.-H. Jang; B. Kahr


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
180 KB
Volume
15
Category
Article
ISSN
0935-9648

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✦ Synopsis


Optically nonlinear single crystals of potassium hydrogen phthalate were grown in the presence of a variety of laser dyes. Up‐conversion fluorescence (as shown in the Figure) in the visible part of the spectrum was observed as a result of two excitation mechanisms involving trapped, oriented luminophores: two‐photon absorption in general orientations, and absorption of the second harmonic of the fundamental beam at 800 nm, when aligned with the phase‐matching direction.


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Single-crystals of potassium hydrogen phthalate (KAP) doped with coumarin 6 (C6) were grown by solution evaporation technique. Powder X-ray diffraction, optical transmission and luminescence measurements were performed. The structure and morphology of the KAP crystals are not changed with the incorp