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Unusual spectroscopic and conformational properties of some spirocyclic oxaziridines

✍ Scribed by Jeffrey Aubé*; Yuguang Wang

Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
142 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis

The proton that bears a 1,3-diaxial relationship to the substituted nitrogen atom of some chiral oxaziridines appears in the NMR spectrum at unusually high field. This observation indicates that an unusual rotamer is substantially populated in these systems.

We and others have been interested in the conformational properties of chiral oxaziridines, especially those

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