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Unusual solvent-effect in stereochemistry of asymmetric epoxidation using a (salen)chromium(III) complex as a catalyst

✍ Scribed by Hirotoshi Imanishi; Tsutomu Katsuki

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
267 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

Epoxidation of conjugated olef'ms has been examined with (salen)ehromium(III) complexes as catalysts. Although (salen)chromium(III) complexes were catalytically less active than the corresponding (salen)manganese(lll) complexes, the reactions with the chromium complexes were found to exhibit interesting solvent-dependent stereochemistry.

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