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Unusual Silicon Coordination Polyhedra: Non-VSEPR Structures of Zwitterionic λ5-Si Silicon(IV) Complexes with an SiS2N2C or SiS2O2C Skeleton

✍ Scribed by Dennis Troegel; Christian Burschka; Sebastian Riedel; Martin Kaupp; Reinhold Tacke

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 315 KB
Volume: 119
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200700785

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Unusual Silicon Coordination Polyhedra:

Unusual Silicon Coordination Polyhedra: Non-VSEPR Structures of Zwitterionic λ5-Si Silicon(IV) Complexes with an SiS2N2C or SiS2O2C Skeleton

✍ Dennis Troegel; Christian Burschka; Sebastian Riedel; Martin Kaupp; Reinhold Tac 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 315 KB

Synthesis and Structural Characterizatio

Synthesis and Structural Characterization of Novel Neutral Hexacoordinate Silicon(IV) Complexes with SiS2O2N2 Skeletons

✍ Stefan Metz; Christian Burschka; Reinhold Tacke 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 461 KB 👁 1 views

## Abstract A series of novel hexacoordinate silicon(IV) complexes with two tridentate dianionic S,N,O ligands was synthesized, starting from Si(NCO)~4~. All the compounds synthesized were structurally characterized by single‐crystal X‐ray diffraction and/or solid‐state NMR spectroscopy. In additio