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Synthesis and Structural Characterization of Novel Neutral Hexacoordinate Silicon(IV) Complexes with SiS2O2N2 Skeletons

✍ Scribed by Stefan Metz; Christian Burschka; Reinhold Tacke


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
461 KB
Volume
2008
Category
Article
ISSN
1434-1948

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✦ Synopsis


Abstract

A series of novel hexacoordinate silicon(IV) complexes with two tridentate dianionic S,N,O ligands was synthesized, starting from Si(NCO)~4~. All the compounds synthesized were structurally characterized by single‐crystal X‐ray diffraction and/or solid‐state NMR spectroscopy. In addition, most of the compounds were characterized by solution NMR spectroscopy.(Β© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)


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Reaction of cupferron [NH 4 L, L = PhN(O)NO -] with tin(IV), complex 2. The tin centers are heptacoordinated in a pentagonal bipyramidal geometry in the dimeric complex 3. diphenyltin(IV) and dimethyltin(IV) halides yields the cupferronato complexes SnL 4 (1), Ph 2 SnL 2 (2) and These complexes inco