Diphenyl diselenide reacts with [CpRh(CO) 2 ] (1) to give the dimer [CpRh(SePh)(l-SePh)] 2 (2), the solid state structure of which has been determined by X-ray analysis; the dimeric structure is retained in solution. In contrast, [Cp\*Rh(CO) 2 ] (4) gives the ionic product [Cp\*Rh(l-SePh) 3 RhCp\*][
Unusual Selectivity in the Thermal Rearrangement-Elimination Reaction of a Carbene Complex in Solution and in the Solid State
β Scribed by Dr. Helmut Fischer; Dipl.-Chem. Andreas Motsch; Dr. Willi Kleine
- Publisher
- John Wiley and Sons
- Year
- 1978
- Tongue
- English
- Weight
- 263 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0044-8249
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The solid-state molecular structure and the conformational behaviour in solution of the 12-membered crown dithioether 8-methyl-1,4-dioxa-7,10-dithiacyclododecane-5,12-dione were studied by x-ray crystallography, 1 H and 13 C NMR spectroscopy and molecular mechanics. The conformational rigidity of so