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Unusual reductive cleavage of 7-oxa-bicyclo[2,2,1]heptane system for the synthesis of tetrahydrofuran derivatives

✍ Scribed by Giovanni Viti; Enzo Perrotta; Danilo Giannotti; Rossano Nannicini


Book ID
108378644
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
669 KB
Volume
53
Category
Article
ISSN
0040-4020

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The Lithium Amide Induced Rearrangement
✍ OdΓ³n Arjona; Roberto Menchaca; Joaquı́n Plumet πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 132 KB

AbstractÐLithium amides induce rearrangement of the title compounds 1 to afford nortricyclanones 4 via a ketocarbene intermediate. Compounds 4 undergo hydride transfer reduction and imino aldol condensation to afford the other observed reaction products.