𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Unusual reactions between chloroketenes and 1,3,5-tri-tert-butylcyclopentadiene

✍ Scribed by Dehmlow, Eckehard Volker ;Bollmann, Christof ;Neumann, Beate ;Stammler, Hans-Georg

Book ID
102904221
Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
554 KB
Volume
1995
Category
Article
ISSN
0947-3440

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Reaction of title compound 1 with dichloroketene resulted in a complex rearrangement to 2 when the ketene was generated from Cl~3~CCOCl/Zn. In contrast, treatment of 1 with the ketene produced from dichloroacetyl chloride/triethylamine gave a bicyclo[3.2.0]heptenone (3) along with acylation product 4. Reaction of monochloroketene with 1 afforded the β€žnormal”︁ endo‐chloro compound 6 which thermally rearranged to the formal Diels‐Alder product 7.

πŸ“œ SIMILAR VOLUMES

Reactions of 1,3,5-Tri-tert-butylcyclope
Reactions of 1,3,5-Tri-tert-butylcyclopentadiene formation of a tetracyclo[5.2.1.02,6.03,10]deca-4,8-diene
✍ Dehmlow, Eckehard V. ;Bollmann, Christof πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 332 KB

Title compound 1 is sterically shielded to such an extent that many "normal" reactions cannot occur. It is possible, however, to prepare the carboxylic acid 2, its acyl chloride 3 and the oxidation product 4. Furthermore, halogen substitutions to yield 5 and 6 and trialkylstannations to give 8a, b c

ChemInform Abstract: Organophosphorus Co
ChemInform Abstract: Organophosphorus Compounds. Part 152. Unusual Addition Reactions of Lithium Alkoxides to 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene.
✍ M. Krein; U. Bergstraesser; C. Peters; S. G. Ruf; M. Regitz πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v