## Abstract Reaction of title compound 1 with dichloroketene resulted in a complex rearrangement to 2 when the ketene was generated from Cl~3~CCOCl/Zn. In contrast, treatment of 1 with the ketene produced from dichloroacetyl chloride/triethylamine gave a bicyclo[3.2.0]heptenone (3) along with acyla
ChemInform Abstract: Unusual Reactions Between Chloroketenes and 1,3,5-Tri-tert- butylcyclopentadiene.
β Scribed by E. V. DEHMLOW; C. BOLLMANN; B. NEUMANN; H.-G. STAMMLER
- Book ID
- 112027567
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Title compound 1 is sterically shielded to such an extent that many "normal" reactions cannot occur. It is possible, however, to prepare the carboxylic acid 2, its acyl chloride 3 and the oxidation product 4. Furthermore, halogen substitutions to yield 5 and 6 and trialkylstannations to give 8a, b c
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v