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Unusual products in aza-cope rearrangements of 1,2-Dihydhoisoquinolines

โœ Scribed by R.G. Kinsman; S.F. Dyke


Book ID
104214995
Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
163 KB
Volume
16
Category
Article
ISSN
0040-4039

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Computational Studies on 3-Aza-Cope Rear
โœ Rainer F. Winter; Guntram Rauhut ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 192 KB ๐Ÿ‘ 2 views

The 3-aza-Cope rearrangements of 3-azoniahexa-1,5-diene (1), 3-azoniahex-1-ene-5-yne (3), and 3-azahex-1-ene-5-yne (5) were investigated up to the coupled-cluster level, CCSD(T), by using a valence triple-zeta basis set. Activation barriers and geometrical parameters of the transition states are pro