Rearrangements of Substituted 3-Aza-1,2,5-hexatrienes. 3. The Scope and Versatility of an Extremely Mild 3-Aza-Cope Reaction
β Scribed by Walters, Michael A.; Hoem, Andrew B.; McDonough, Colleen S.
- Book ID
- 121443809
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 282 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
The 3-aza-Cope rearrangements of 3-azoniahexa-1,5-diene (1), 3-azoniahex-1-ene-5-yne (3), and 3-azahex-1-ene-5-yne (5) were investigated up to the coupled-cluster level, CCSD(T), by using a valence triple-zeta basis set. Activation barriers and geometrical parameters of the transition states are pro
Aza-Wittig reaction of N-acrylic phospha-x5-azenes with aldehydes gives 3-ethoxycarbonyl 2-aza-1,3-dienes in very high yields. Compounds containing the 2-aza-1,3-diene group represent a very important class of derivatives as a result of their potential as key intermediates in organic synthesis. Part