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Unusual low-energy isomers for simple radical cations

✍ Scribed by Michael J. Frisch; Krishnan Raghavachari; John A. Pople; Willem J. Bouma; Leo Radom


Book ID
107941960
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
545 KB
Volume
75
Category
Article
ISSN
0301-0104

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Oxidation potentials of Ξ±-aminoalkyl rad
✍ Danial D.M. Wayner; Joseph J. Dannenberg; David Griller πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 English βš– 193 KB

or-aminoalkyl radicals were generated using modulated photolysis and were detected electrochemicalIy; their oxidation potentials were used to estimate bond dissociation energies of radical cations in solution. a-aminoalkyl radicals are potent one-electron reducing agents in solution. Their gas-phase