𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Three new isomers of [C2H6O]+˙: The radical cations [CH3O(H)CH2]+˙, [CH3CHOH2]+˙ and a low-energy isomer of unassigned structure

✍ Scribed by Peter C. Burgers; John L. Holmes; Johan K. Terlouw; Ben van Baar

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
508 KB
Volume
20
Category
Article
ISSN
1076-5174

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Stable C2H5X+˙ (X=Cl, Br) radical cation
Stable C2H5X+˙ (X=Cl, Br) radical cations of structure [CH3CHXH+˙]: Their energetics and dissociation characteristics
✍ John L. Holmes; Peter C. Burgers; Johan K. Terlouw; Helmut Schwarz; Bernhard Cio 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 369 KB

A new radical cation having the methyl carbene type structure [CH3CHCIH]" has been characterized in the gas phase. It is readily generated by the dissociative ionization [CH3CHClC02H]" + C02+[CH3CHC1H]". Its enthalpy of formation has been estimated to be 951 kJ mol-l, close to that of [CH3CH2CI]". T

Structures and stabilities of C3H4O+˙ is
Structures and stabilities of C3H4O+˙ isomers: A G2 theoretical study
✍ Michael L. McKee; Leo Radom 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 577 KB

Six stable isomers and two transition structures were characterized on the C3H,0+' potential energy surface using the G2 procedure. Heat capacity corrections were made to allow the direct calculation of heats of formation at 1298 K. The most stable isomer is the methylketene radical cation (1, AH, 2