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Unusual chemically induced nuclear spin polarization in reactions of sodium naphthalene with alkyl halides

โœ Scribed by Garst, John F.; Cox, Richard H.; Barbas, John T.; Roberts, Rex D.; Morris, John I.; Morrison, Robert C.

Book ID
127319205
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
480 KB
Volume
92
Category
Article
ISSN
0002-7863

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โœ F.J. Adrian ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 325 KB

It is proposed that the high field IgF nuclear spin polarization observed in fhe producr of the reaction of tluorobenzyl halides with sodium naphthalene is not due to the usual radical pair mechanism, but rather to a build up of electron spin polarization in the intermediate benzyl radical combined