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Unusual Case of Catalysis by Palladium Clusters.

✍ Scribed by I. P. Stolarov; Zh. V. Dobrokhotova; G. N. Kryukova; N. Yu. Kozitsyna; A. E. Gekhman; M. N. Vargaftik; I. I. Moiseev

Publisher
John Wiley and Sons
Year
2006
Weight
15 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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## Abstract A novel asymmetric catalysis __via__ a palladium(II)/palladium(IV) cycle has been developed by utilizing a chiral spiro bis(isoxazoline) ligand (SPRIX). Intramolecular chlorinative cyclization of 1,6‐enynes catalyzed by a palladium‐SPRIX complex proceeded enantioselectively to afford α‐