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Supramolecular Cluster Catalysis: A Case Study of Benzene Hydrogenation

✍ Scribed by Bruno Therrien; Ludovic Vieille-Petit; Mathieu Tschan; Vladimir B. Romakh; Georg Suess-Fink


Publisher
John Wiley and Sons
Year
2004
Weight
52 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract The diphosphane‐substituted clusters [Ru~3~(CO)~10~(dppe)] and [Ru~3~(CO)~8~(dppe)~2~] [dppe = 1,2‐bis(diphenylphosphanyl)ethane] are shown to catalytically hydrogenate diphenylacetylene. This process is highly solvent‐dependent with fragmentation dominating in low‐polarity solvents, wh