Unusual 1,2-migration in organoaluminiun chemistry, promoted by BF3.OEt2.
✍ Scribed by Alex Alexakis; Jezia Hanaïzi; Denis Jachiet; Jean-F Normant; Loïc Toupet
- Book ID
- 104222051
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 220 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
BF 3 ÁOEt 2 -catalyzed methyl group migration of 4-methyl-4-tert-butyldioxycyclohexadienone, which is obtained by ruthenium-catalyzed oxidation of p-cresol with tert-butyl hydroperoxide, in hexafluoro-2propanol/toluene gave toluquinone efficiently. The reaction can be applied to the regio-selective