✦ LIBER ✦

Synthesis of 2-substituted quinones, vitamin K3, and vitamin K1 from p-cresol. BF3·OEt2-catalyzed methyl migration of 4-tert-butyldioxycyclohexadienones

✍ Scribed by Shun-Ichi Murahashi; Akiko Fujii; Yasutaka Inubushi; Naruyoshi Komiya

Book ID: 104097555
Publisher: Elsevier Science
Year: 2010
Tongue: French
Weight: 466 KB
Volume: 51
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2010.02.134

No coin nor oath required. For personal study only.

✦ Synopsis

BF 3 ÁOEt 2 -catalyzed methyl group migration of 4-methyl-4-tert-butyldioxycyclohexadienone, which is obtained by ruthenium-catalyzed oxidation of p-cresol with tert-butyl hydroperoxide, in hexafluoro-2propanol/toluene gave toluquinone efficiently. The reaction can be applied to the regio-selective shortstep syntheses of vitamin K 3 and vitamin K 1 from p-cresol.

📜 SIMILAR VOLUMES

ChemInform Abstract: Synthesis of 2-Subs

ChemInform Abstract: Synthesis of 2-Substituted Quinones, Vitamin K3, and Vitamin K1 from p-Cresol. BF3·OEt2-Catalyzed Methyl Migration of 4-tert-Butyldioxycyclohexadienones.

✍ Shun-Ichi Murahashi; Akiko Fujii; Yasutaka Inubushi; Naruyoshi Komiya 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

Metalloporphyrin-Catalyzed Oxidation of

Metalloporphyrin-Catalyzed Oxidation of 2-Methylnaphthalene to Vitamin K 3 and 6-Methyl-1,4-naphthoquinone by Potassium Monopersulfate in Aqueous Solution

✍ Song, Rita; Sorokin, Alexander; Bernadou, Jean; Meunier, Bernard 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 181 KB

Synthesis of 2-methyl-1,4-naphthoquinone

Synthesis of 2-methyl-1,4-naphthoquinone (vitamin K3) using nanostructured gold catalysts in acetic acid and in supercritical carbon dioxide

✍ Shimanskaya, E. I.; Doluda, V. Yu.; Sul’man, E. M. 📂 Article 📅 2014 🏛 SP MAIK Nauka/Interperiodica 🌐 English ⚖ 250 KB

Catalytic Synthesis of 2-Methyl-1,4-Naph

Catalytic Synthesis of 2-Methyl-1,4-Naphthoquinone (Vitamin K 3 ) Over Silica-Supported Aminomethyl Phosphine-Ru(II), Pd(II), and Co(II) Complexes

✍ Uruş, Serhan; Keleş, Mustafa; Serindağ, Osman 📂 Article 📅 2010 🏛 Taylor and Francis Group 🌐 English ⚖ 407 KB

Circumvention of Adriamycin resistance:

Circumvention of Adriamycin resistance: effect of 2-methyl-1,4-naphthoquinone (vitamin K3) on drug cytotoxicity in sensitive and MDR P388 leukemia cells

✍ Parekh, Hemant K.; Mansuri-Torshizi, Hassan; Srivastava, T.S.; Chitnis, Manik P. 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 964 KB

Synthesis of Silica-Supported Platinum(I

Synthesis of Silica-Supported Platinum(II) and Nickel(II) Complexes ofBis(Diphenylphosphinomethyl)Amino Ligand: Applications as Catalysts for the Synthesis of 2-Methyl-1,4-Naphthoquinone (Vitamin K3)

✍ Serhan Uruş; Mustafa Keleş; Osman Serindağ 📂 Article 📅 2010 🏛 Springer 🌐 English ⚖ 505 KB