Untersuchungen über die Wirkung synthetischer Antioxidantien im Vergleich zu Vitamin E und Selen im Futter von Regenbogenforellen (Salmo gairdnerii R.)
✍ Scribed by Oberbach, H. ;Hartfiel, W.
- Publisher
- John Wiley and Sons
- Year
- 1988
- Weight
- 496 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0931-5985
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✦ Synopsis
The straight-line dependence between the log r I H p number values and the mobile phase com osition confirms our previous discussion concerning F('? The analogical straight-line correlations are widely observed and commented in physical chemistry of the classical transitionmetal-coordinated complexes '"; they are common with these complexes, which occur in the few different quantitative proportions. Fig. 2.The log K ~H ~ vs. the volume fraction of ethyl acetate (v.f. EA) plot Now it is the right place to mention that eqs. (4) and (22)-(25) seem in a justified way closely related to the renowned Soczewiriski relationship [see eq. ( 5 ) ] ,
as the RM magnitude from that equation also describes an equilibrium within the chromatographic spot, and the right-hand sides of all the above mentioned relationships are in fact reciprocally equivalent.
Last but not least: Eqs. ( 18) and ( 19) can well be replaced by the following ones: in this sense that the respective equilibrium constants KA& and GAS, for them derived equal those from Table 4.
All the questions handled in the paragraphs 1) and 2) aimed to stress the mechanistic possibilities of the "binary solutions" model. Thus the utilitarian aspect of this approach seems rather indisputable, and its good agreement with the principal theories of the flat-bed chromatography demonstrated.
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