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Untersuchungen zur Sulfochlorierung von Paraffinen. IX. Substitutionsregelmäßigkeiten bei der Sulfochlorierung verzweigter Paraffine

✍ Scribed by Dipl.-Chem. D. Estel; Dr. K. Mateew; Prof. Dr. W. Pritzkow; Dr. W. Schmidt-Renner

Publisher: John Wiley and Sons
Year: 1981
Tongue: English
Weight: 387 KB
Volume: 323
Category: Article
ISSN: 1615-4150
DOI: 10.1002/prac.19813230211

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✦ Synopsis

Studies on Sulphochlorination of Paraffins. IX. Regularities of the Sulphochlorination of Branched‐chain Paraffins

In the cases of 2‐methylbutane and 2‐methylpentane the formation of tertiary sulphochlorides in the sulphochlorination of the parent hydrocarbons could be established by means of ^13^C‐n.m.r.‐spectroscopy. The relative rates of the various CH‐bonds in 2‐methylbutane, 2‐methylpentane and 3‐methylpentane in the sulphochlorination reaction were determined. The relative rates of the tertiary CH‐bonds in the sulphochlorination were considerably lower than the corresponding values for the chlorination of the branched‐chain paraffins.

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