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Untersuchungen in der Benztropylium-Reihe XIII: Hückel-MO's benzologer Tropylium-Kationen

✍ Scribed by G. Naville; Hansruedi Strauss; E. Heilbronner


Publisher
John Wiley and Sons
Year
1960
Tongue
German
Weight
499 KB
Volume
43
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

The HÜCKEL‐type LCAO‐MO's Φ~j~ and their corresponding eigenvalues E~j~ have been tabulated for the seven lowest members of the benzologous tropylium cations, together with their charge densities, bond orders and free valencies.


📜 SIMILAR VOLUMES


Untersuchungen in der Benztropylium-Reih
✍ Doris Meuche; Hansruedi Strauss; E. Heilbronner 📂 Article 📅 1958 🏛 John Wiley and Sons 🌐 German ⚖ 736 KB

## Abstract It is shown that the experimentally determined pK‐values and the position of the long wave absorption bands of the tropylium cation and some of its benzologues correlate closely with the theoretical predictions drawn from simple LCAO MO models for these compounds. The observed correlati