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Unsymmetrical Hybrid Ferrocene-Based Phosphine-Phosphoramidites: A New Class of Practical Ligands for Rh-Catalyzed Asymmetric Hydrogenation.

✍ Scribed by Xiang-Ping Hu; Zhuo Zheng


Publisher
John Wiley and Sons
Year
2005
Weight
26 KB
Volume
36
Category
Article
ISSN
0931-7597

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Practical by Ligand Design: A New Class
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## Abstract A new class of low‐cost and easy‐to‐prepare monodentate phosphoramidite ligands (CydamPhos) has been developed from readily accessible and cheap __trans__‐1,2‐diaminocyclohexane as starting material through a three‐step transformation. This type of ligands exhibited excellent enantiosel