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Catechol-Based Phosphoramidites: A New Class of Chiral Ligands for Rhodium-Catalyzed Asymmetric Hydrogenations.

✍ Scribed by Rob Hoen; Michel van den Berg; Heiko Bernsmann; Adriaan J. Minnaard; Johannes G. de Vries; Ben L. Feringa

Publisher
John Wiley and Sons
Year
2004
Weight
194 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract A new class of low‐cost and easy‐to‐prepare monodentate phosphoramidite ligands (CydamPhos) has been developed from readily accessible and cheap __trans__‐1,2‐diaminocyclohexane as starting material through a three‐step transformation. This type of ligands exhibited excellent enantiosel